Access to side-chain carbon information in deuterated solids under fast MAS through non-rotor-synchronized mixing.
نویسندگان
چکیده
We demonstrate the accessibility of aliphatic (13)C side chain chemical shift sets for solid-state NMR despite perdeuteration and fast MAS using isotropic, non-rotor-synchronized (13)C-(13)C mixing. Combined with amide proton detection, we unambiguously and sensitively detect whole side chain to backbone correlations for two proteins using around 1 mg of sample.
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ورودعنوان ژورنال:
- Chemical communications
دوره 52 2 شماره
صفحات -
تاریخ انتشار 2016